期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 41, 页码 6769-6772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00923a
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资金
- Australian Government
- University of Nottingham
- Royal Society
- EPSRC [EP/K038869/1]
- ERC
- EPSRC [EP/P001386/1, EP/I020942/1, EP/I011870/2, EP/I011870/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/I011870/2, 1225659, EP/I020942/1, EP/K038869/1, EP/C528964/1, EP/P001386/1, EP/I011870/1] Funding Source: researchfish
High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}(2)] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.
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