4.7 Article

Catalytic conversion of methanol/ethanol to isobutanol - a highly selective route to an advanced biofuel

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CHEMICAL COMMUNICATIONS
卷 52, 期 29, 页码 5202-5204

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01599a

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  1. Engineering and Physical Sciences Research Council [EP/K014854/1, 1501078, 1501287] Funding Source: researchfish
  2. EPSRC [EP/K014706/2, EP/K014854/1] Funding Source: UKRI

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Catalysts based on ruthenium diphosphine complexes convert methanol/ethanol mixtures to the advanced biofuel isobutanol, with extremely high selectivity (>99%) at good (>75%) conversion via a Guerbet-type mechanism.

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