期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 76, 页码 11363-11365出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06125g
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资金
- Fonds der Chemischen Industrie via a Liebigstipendium
For decades, akuammiline alkaloids have attracted synthetic chemists due to their intriguing molecular architecture. Among the different structural elements embedded in their carboskeleton, the methano-quinolizidine system constitutes the signature structural element of this alkaloid family. Herein, we describe a novel synthetic access to this system which relies on a [2,3]-Stevens rearrangement and results in the formal synthesis of strictamine.
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