期刊
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
卷 87, 期 -, 页码 -出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jfca.2019.103389
关键词
Deep eutectic solvent; Organophosphorus pesticides; Fruit Juice; Desirability function; HPLC
A deep eutectic solvent-based ultrasound-assisted liquid-liquid microextraction (DES-UALLME) followed by quantitative analysis using HPLC-UV has been developed for the determination of organophosphorus pesticides (phosalone and chlorpyrifos) in fruit juice samples (red grape juice and sour cherry juice). In DES-UALLME, ultrasonication was applied to transfer the aggregated of DES into tiny droplets. The parameters that influence on extraction efficiency were studied and optimized by central composite design (CCD) in combination with a desirability function approach. The optimum conditions obtained by multivariate optimization were 408 mu L of DES, 560 mu L of THF, pH of 5.92, and an ultrasonication time of 12.31 min. Under the optimized condition, wide linear range (1-500 ng(-1)), low detection limits (0.070 and 0.096 ng mL(-1)), high enrichment factors, and good extraction recoveries were obtained. The procedure was successfully applied for the determination of phosalone and chlorpyrifos in red grape juice and sour cherry juice samples with satisfactory relative recoveries (87.3-116.7 %).
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