期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 51, 页码 8018-8021出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02816k
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资金
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [24350029, 2406, 24107004]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - World Premier International Research Center Initiative (WPI), MEXT, Japan
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-FG02-07ER15909]
- Grants-in-Aid for Scientific Research [15H03786, 24107004] Funding Source: KAKEN
A mu-oxido-bridged triruthenium complex (RuT2+), formed by air oxidation of a previously reported monoruthenium water-oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s(-1) and 610, respectively. The crystal structures of RuT2+ and its one-electron oxidized RuT3+ are also reported.
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