4.7 Article

Visible-light-driven photocatalytic water oxidation catalysed by iron-based metal-organic frameworks

期刊

CHEMICAL COMMUNICATIONS
卷 52, 期 29, 页码 5190-5193

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00730a

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资金

  1. ACCEL Project'' from the Japan Science and Technology Agency
  2. Ministry of Education, Culture, Sports, Science and Technology of Japan [25410241, 15K17903]
  3. Global Research Program of the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology (MEST), Korea [2010-00339]
  4. JSPS Research Fellowships
  5. Grants-in-Aid for Scientific Research [25410241] Funding Source: KAKEN

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An iron-based metal-organic framework, MIL-101(Fe), promotes photocatalytic water oxidation to produce oxygen from aqueous silver nitrate solution under visible-light irradiation. The finely dispersed iron-oxo clusters embedded as nodes of the porous framework would contribute importantly to the efficient promotion of the reaction as compared to bulk hematite (alpha-Fe2O3).

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