期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 565, 期 -, 页码 197-204出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2019.12.113
关键词
2D alpha-MoO3 phase; Solid state reaction; Li-ion battery; Stable performance; High capacity
资金
- CONACYT-SENER [274314]
- Vellore institute of technology (VIT University - Vellore campus)
Engineering two dimensional (2D) materials at atomic level is a key factor to achieve enhanced electrochemical Li-ion storage properties. This work demonstrates that single crystals of orthorhombic alpha-MoO3 phase can preferentially grow with a 2D nanoarchitecture via a ball-milling process, followed by heat treatment at elevated temperature. Detailed FE-SEM and TEM micrographs proved the 2D architecture of alpha-MoO3 nanoparticles and Raman spectroscopy evidenced the active vibration modes that correspond to the orthorhombic a-MoO3 phase. Single crystalline MoO3 belts depicted high intensity of (0 2 0) and (0 4 0) indexed planes indicating a preferential arrangement. As Li-ion host anode, the 2D alpha-MoO3 nanostructure delivered high reversible specific discharge capacity of similar to 540 mA h g(-1) at 0.2 C-rate with 99.9% coulombic efficiency as well as 63% capacity retention after 200 charge-discharge cycles. An excellent reversible Li-ion storage performance (high capacity, longer cycle life and good rate capability) was attributed to the 2D alpha-MoO3 arrangement consists of MoO6 octahedron by corner sharing chains. (C) 2019 Elsevier Inc. All rights reserved.
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