期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 15, 页码 3187-3190出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09688j
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资金
- National Science Council
- Ministry of Education, Taiwan
Gold-catalyzed [2+2+2]-cycloadditions of two discrete ynamides and one nitrile afford 2,4-diaminopyridine derivatives that are not readily prepared from typical low-valent-metal catalysts. Our mechanistic analysis reveals that the reaction chemoselectivity is controlled by the types of sulfonamides of ynamides.
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