期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 14, 页码 2909-2912出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09533f
关键词
-
资金
- Spanish MINECO [SAF2013-41943-R]
- ERDF
- European Research Council [340055]
- Xunta de Galicia [GRC2013-041]
Aldehydes can be alpha-alkylated with allenamides by the combined action of an organocatalyst and a gold complex. The reaction requires the simultaneous generation of an enamine and a gold-activated allenamide. Importantly, by using a chiral amine as organocatalyst it is possible to obtain aldehyde products featuring all-carbon quaternary stereocenter at their alpha-position, with moderate to good levels of enantioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据