4.7 Article

Synthesis and electrochemical properties of Li1.3Nb0.3V0.4O2 as a positive electrode material for rechargeable lithium batteries

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CHEMICAL COMMUNICATIONS
卷 52, 期 10, 页码 2051-2054

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08034g

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The binary system, xLi(3)NbO(4)-(1 - x)LiVO2, was first examined as an electrode material for rechargeable lithium batteries. The sample (x = 0.43) crystallizes into a cation-disordered rocksalt structure and delivers a reversible capacity of ca. 230 mA h g(-1), which originates from V3+/V5+ redox with electrochemically inactive niobium ions.

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