期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 97, 页码 13963-13966出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08535k
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资金
- AstraZeneca
- Stockholm Brain Institute
- Swedish Research Council
- Knut and Alice Wallenberg Foundation
Nucleophilic F-18-fluorination of bromodifluoromethyl derivatives was performed using [F-18] Bu4NF in the presence of DBU(1,8-diazabicyclo[5.4.0]undec-7-ene). This novel procedure provided a diverse set of [F-18] trifluoroacetamides in good to excellent radiochemical conversions. A mechanism where DBU acts as organomediator in this transformation is proposed.
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