期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 22, 页码 4179-4182出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10245f
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资金
- DST New Delhi [EMR/2015/000061]
- IISER Bhopal
- UGC, New Delhi
A catalytic system consisting of bis(4-methoxyphenyl)selenide and 4-(dimethylamino)pyridine (DMAP) has been developed for the regio-selective synthesis of medium-sized bromo/iodo lactones and bromooxepanes possessing high transannular strain. Se-77 NMR, mass spectrometry and theoretical studies reveal that the reaction proceeds via a quaternary selenium intermediate.
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