期刊
JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 65, 期 6, 页码 3240-3251出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.0c00290
关键词
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资金
- National Natural Science Foundation of China [NNSFC 51603019]
- Outstanding Young Talents Funding Project of the Science and Technology Development Plan of Jilin Province [20180520164JH]
- Science and Technology Project of the Education Department of Jilin Province in the 13th Five-Year [JJKH20200684KJ]
The solubility data of edaravone in fourteen neat solvents (water, methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, sec-butanol, n-pentanol, acetone, acetonitrile, dichloromethane, ethyl acetate, and 1,4-dioxane) and three binary solvent mixtures (methanol + water, ethanol + water, and isopropanol + water) were determined by the gravimetric method from 283.15 to 323.15 K. The co-solvency phenomenon was found in the mixed solvents of (ethanol + water) and (isopropanol + water). The solute-solvent and solvent-solvent interactions were analyzed by the KAT-LSER model. In addition, the solubility data were correlated by the modified Apelblat model, Jouyban-Acree model, and Apelblat-Jouyban-Acree model. To choose the best model for correlating the edaravone solubility, the Akaike information criterion values and Akaike weights were calculated for each thermodynamic model.
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