期刊
JOURNAL OF APPLIED PHYSICS
卷 127, 期 18, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/5.0004125
关键词
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资金
- Helmholtz Association
- Deutsche Forschungsgemeinschaft (DFG) [HA 1344/43-1, WE 2623/14-1]
- Helmholtz-Zentrum Berlin [191-07848-ST]
High entropy oxides (HEOs) are a recently introduced class of oxide materials, which are characterized by a large number of elements (i.e., five or more) sharing one lattice site, which crystallize in a single phase structure. One complex example of the rather young HEO family is the rare-earth transition metal perovskite high entropy oxides. In this comprehensive study, we provide an overview of the magnetic properties of three perovskite type high entropy oxides. The compounds have a rare-earth site that is occupied by five different rare-earth elements, while the transition metal site is occupied by a single transition metal. In this way, a comparison to the parent binary oxides, namely, the orthocobaltites, -chromites, and -ferrites, is possible. X-ray absorption near edge spectroscopy, magnetometry, and Mossbauer spectroscopy are employed to characterize these complex materials. In general, we find surprising similarities to the magnetic properties of the binary oxides despite the chemical disorder on the rare-earth site. However, distinct differences and interesting magnetic properties are also observed such as noncollinearity, spin reorientation transitions, and large coercive fields of up to 2T at ambient temperature. Both the chemical disorder on the rare-earth A-site and the nature of the transitional metal on the B-site play an important role in the physical properties of these high entropy oxides.
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