Self-supported core-shell heterostructure MnO2/NiCo-LDH composite for flexible high-performance supercapacitor

Nickel cobalt layered double hydroxides (NiCo-LDHs) nanosheets (NSs) were synthesized on a flexible carbon cloth (CC) substrate by a simple hydrothermal method. Then the manganese dioxide (MnO2) NSs were directly deposited on the NiCo-LDH/CC to form three-dimensional (3D) self-supported core-shell MnO2/NiCo-LDH/CC flexible electrodes. The MnO(2 )NSs with three different loading amount on NiCoLDH/CC substrate, named MnO2-1/NiCo-LDH/CC, MnO2-2/NiCo-LDH/CC and MnO2-3/NiCo-LDH/CC, were hydrothermally synthesized in 0.01 M, 0.02 M and 0.03 M potassium permanganate (KMnO4) solution, respectively. The morphology and electrochemical performance of these obtained composite electrodes were observed and analyzed. The MnO2 -2/NiCo-LDH/CC electrode exhibits a capacitive performance of 312 F g(-1) at 0.2 A g(-1) (937 mF cm(-2) at 1 mV s(-1)) and maintains 97% of the original capacitance after 5000 charge-discharge cycles. The good mechanical stability and excellent cycle performance of MnO2-2/NiCo-LDH/CC electrode is benefit from the numerous channels for rapid electron transport provided by the large specific surface area and self-supported of NiCo-LDH nanoflakes. Therefore, the MnO2-2/NiCo-LDH/CC composite electrode is a potential candidate in wearable energy storage device. (C) 2020 Elsevier B.V. All rights reserved.