期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 823, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.153690
关键词
Polyol synthesis; Nanocrystalline; Tungsten oxide; Electrochromism
资金
- LUMAQ International Associate Laboratory (LIA)
Tungsten trioxide, synthetized as nanoparticles (NPs), then shaped as thin or thick films, has attracted considerable attention as a typical electrochromic material. Herein, the synthesis of WO3 nanoparticles by the polyol process followed or not by heat-treatments under air or argon, has allowed us to compare the electrochromic activity of powders with different morphologies and oxygen-deficiencies. Only the finest particles associated with pseudo-cubic structure due to a large oxygen-deficiency - on the contrary to the larger particles with standard monoclinic structure and W/O stoichiometric ratio - lead to films showing intense electrochromic color change from a whitish (bleached state) to a dark blue (colored state). Additionally, the as-prepared films exhibit quite fast electrochromic performance and satisfying cycling stability. The sub-stoichiometric nanoparticles prepared from polyol synthesis are of great potential for electrochromic applications. (C) 2020 Elsevier B.V. All rights reserved.
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