期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 46, 期 48, 页码 24721-24741出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.03.135
关键词
Syngas; Heterogeneous catalytic process; Fischer Tropsch synthesis; Microkinetic modeling; Cobalt catalyst
资金
- Graduate College KMUTNB, Thailand Research Fund [PHD59I0026]
- PTT Research and Technology Institute
A systematic microkinetic model was proposed for cobalt-catalyzed Fischer Tropsch synthesis, accurately predicting product distribution trends and hydrogen utilization. High model accuracy was achieved in material balance, with an error of 10(-10)-10(-3)%.
Fuels production from syngas via Fischer Tropsch synthesis (FTs) is an alternative technology for clean energy production. The microkinetic model is a promising approach for gaining insight into FTs activity. In this study, a systematic microkinetic model was proposed to develop a process for cobalt-catalyzed FTs. All possible elementary reactions based on the carbide mechanism and characteristics of catalyst sites were considered in the kinetic model. The effects of the reaction rate constant, reaction pathways, and H-2 to CO ratio were represented by a kinetic parameter, reaction path, and operating parameter, respectively. The model could accurately predict product distribution trends, with an R-2 value and mean absolute relative residuals percentage of 0.91-0.93 and 5-43%, respectively, in comparison with experimental data. Hydrogen utilization was predicted and analyzed. High model accuracy was achieved, with a 10(-10)-10(-3)% error in the material balance. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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