Effects of different sintering additives on the synthesis of γ-Y2Si2O7 powders

Pure gamma-Y2Si2O7 powders were synthesized by the solid-liquid reaction method using Y2O3 and SiO2 powders with Li2O, MgO or Al2O3 additives. The effects of the metallic ions Li+, Mg2+ and Al3+ on the synthesis process were systematically investigated by X-ray diffraction and differential scanning calorimetry. The chemical kinetics of the Y2Si2O7 synthetic process was calculated to illuminate the influences of the different metallic ions on the formation of silicate. The results indicate that the additives could effectively reduce the synthesis temperature by 100-300 degrees C. The apparent activation energy of the synthetic reaction was reduced by 79.75%, 65.16%, or 56.77% when 6 mol.% of Li2O, MgO, or Al2O3 was added, respectively, and the reaction rate was also significantly increased. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.