期刊
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES
卷 28, 期 10, 页码 799-807出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/1536383X.2020.1762578
关键词
Selective oxidation; styrene oxidation; cobalt phthalocyanine; cobalt phthalocyanine; MWCNTs composites
类别
资金
- National Natural Science Foundations of China [21876015, 21703019]
A novel tert-butyl hydroperoxide tetrasubstituted cobalt phthalocyanine (CoPc(OC10H14N)(4)) was synthesized by the classical phthalonitrile method. Subsequently, the cobalt phthalocyanine (CoPc) was immobilized on the multi-walled carbon nanotubes (MWCNTs) by ultrasonic impregnation method to obtain CoPc(OC10H14N)(4)/MWCNTs composites. The obtained composites were characterized by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM) and diffuse reflectance spectra (DRS) techniques. Using tert-butyl hydroperoxide (TBHP) as an environmentally friendly oxidant, CoPc(OC10H14N)(4)/MWCNTs composites can be used as effective catalysts for the epoxidation of styrene. The effects of various variables, such as the mass ratio of CoPc(OC10H14N)(4)/MWCNTs, reaction time, temperature, molar ratio of substrate/oxidant and the amount of catalyst on the catalytic capability were evaluated. The conversion of styrene reached 97.15%, and the epoxidation product achieved the selectivity of 84.44% under the optimal reaction conditions.
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