期刊
FOOD CHEMISTRY
卷 310, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2019.125934
关键词
Xylooligosaccharides; Lignocellulosic acidolysis solution; Decolorization; Amberlite XAD-16N; Adsorption-selectivity
资金
- National Key R&D Program of China [2017YFD0601001]
- Key Research and Development Program of Jiangsu [BE2015758]
Xylooligosaccharides (XOS) are booming in food, pharmacy and feed industries that they have attracted great interest in the high-value utilization of lignocellulose. Selective acidolysis dominates the commercial production of XOS except for intractable color contaminations derivate from ligoncellulosic degradation. Based on a detailed kinetics and thermodynamics investigation, Amberlite XAD-16N was designated as preferred decolorant because of its high adsorption-selectivity for XOS and the colored contaminants. The adsorption of the main compositions in lignocellulosic acidolysis solution was well described by Langmuir models, the kinetics were clearly fitted by Pseudo-second-order model, showing that the adsorption was controlled by electron sharing/transfer between the resin cross-linking groups and colorant. The adsorption mechanism was also verified by the adsorption-simulation of three detected typical colorants. The thermodynamics clearly indicated a spontaneous endothermic reaction. This study provides an important approach for industrial technology development to not only xylooligosaccharides production and lignocellulosic acidolysis, but also Amberlite XAD-16N adsorbent.
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