期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 29, 页码 4606-4611出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000691
关键词
Cycloaddition; Heterocycles; Homogeneous catalysis; Synthetic methods; Ruthenium
资金
- SERB, DST
- CSIR, New Delhi
- UGC, New Delhi
- IIT Ropar
Ru-II-catalyzed intermolecular double [2+2+2] cycloadditions of 1,6-diynes and alkynylthiocyanates have been developed for the synthesis of 2-aryl thiopyridines. Aryl thiocyanates were isolated chemoselectively as a result of initial intermolecular [2+2+2] cycloaddition product. The method offers operational simplicity and is atom economical in nature.
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