期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 14, 页码 2110-2115出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202000162
关键词
Eosin Y; Photoredox catalysis; Sulfanylation; Synthetic methods; Thiols
资金
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- FAPERGS [PqG 17/2551-0000987-8]
- CNPq
- FINEP
A metal-free method for the synthesis of 3-sulfanyl indolizines from thiols and 2-arylindolizines, is reported. The reaction is mediated by eosin Y under blue LED light irradiation and uses atmospheric oxygen as oxidant. By the use of a catalytic amount of I-2, the corresponding 1,3-bis-sulfanyl indolizines are obtained, in good yields.
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