期刊
COMMUNICATIONS IN THEORETICAL PHYSICS
卷 72, 期 6, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/1572-9494/ab8a23
关键词
Poisson-Boltzmann theory; ion correlation; ionic solution; field-theoretic approach; mean field theory
资金
- Strategic Priority Research Program of Chinese Academy of Sciences [XDA17010504]
- National Natural Science Foundation of China [11774357, 11947302]
- CAS Biophysics Interdisciplinary Innovation Team Project [2060299]
The Poisson-Boltzmann (PB) theory is one of the most important theoretical models describing charged systems continuously. However, it suffers from neglecting ion correlations, which hinders its applicability to more general charged systems other than extremely dilute ones. Therefore, some modified versions of the PB theory are developed to effectively include ion correlations. Focused on their applications to ionic solutions, the original PB theory and its variances, including the field-theoretic approach, the correlation-enhanced PB model, the Outhwaite-Bhuiyan modified PB theory and the mean field theories, are briefly reviewed in this paper with the diagnosis of their advantages and limitations.
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