DMMP pyrolysis and oxidation studies at high temperature inside a shock tube using laser absorption measurements of CO

Dimethyl methyl phosphonate (DMMP) is an organo-phosphorous compound (OPC) used as a fire suppressant and a simulant for sarin, a chemical warfare agent. There exists a critical need to gather combustion data at high heating rate and high temperatures conditions, similar to what exists during destruction process of chemical weapons. In the present work, DMMP pyrolysis and oxidation were carried out behind reflected shock waves at temperatures of 1300-1700 K and pressures of 1.5-1.8 mu m. Lean, stoichiometric, and rich DMMP mixtures (Phi= 0.23, 0.5, 1, 2) were investigated for oxidation experiments. Laser absorption spectroscopy utilizing a quantum cascade laser near 4.9 pm was used to measure intermediate CO concentration formed during the pyrolysis and oxidation processes. To the best of our knowledge, we present the first intermediate concentration data at the reported conditions for DMMP. A tentative kinetic model, based on the AramcoMech2.0 mechanism with Lawrence Livermore National Lab (LLNL)'s OPC incineration chemistry, was utilized in Chemkin-Pro to predict CO yield during the processes. The model provided fair prediction of CO yield during DMMP pyrolysis, however, overpredicted the CO yield for oxidation. Sensitivity and rate of production analyses were carried out to understand important reactions leading to CO formation. (C) 2019 The Combustion Institute. Published by Elsevier Inc. All rights reserved.