Effect of Ligand Field Strength on the Spin Crossover Behaviour in 5-X-SalEen (X=Me, Br and OMe) Based Fe(III) Complexes

The reaction of Fe(NCS)(3) prepared in situ in MeOH with 5-X-SalEen ligands (5-X-SalEen=condensation product of 5-substituted salicylaldehyde and N-ethylethylenediamine) provided three Fe(III) complexes, [Fe(5-X-SalEen)(2)]NCS; X=Me (1), X=Br (2), X=OMe (3). All the complexes reveal similar structural features but a very different magnetic profile. Complex 1 shows a gradual spin crossover while complexes 2 and 3 show a sharp spin transition. The T-1/2 for complex 2 is 237 K while for complex 3 it is much higher with a value of 361 K. The spin transition temperature is shifted towards higher temperature with increasing electron-donation ability of the ligand substituents. This experimental observation has been rationalized with DFT calculations. UV-Vis and cyclic voltammetry studies support the fact that the electron density on the ligand increases from Me to Br to OMe substituents. To understand the change in spin states, temperature-dependent EPR spectra have been recorded. The spin state equilibrium in the liquid state has been probed with Evans NMR spectroscopic method, and thermodynamic parameters have been evaluated for all complexes.