期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 54, 页码 12454-12471出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202001952
关键词
cobaloxime; decarboxylative; dual catalysis; hydrogen evolution; photoredox
资金
- National Science Foundation [CHE-1800147]
- Kansas Bioscience Authority Rising Star program
- NSF Academic Research Infrastructure Grant [9512331]
- NIH Shared Instrumentation Grant [S10RR024664]
- NSF Major Research Instrumentation Grant [0320648]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0320648] Funding Source: National Science Foundation
- Div Of Biological Infrastructure
- Direct For Biological Sciences [9512331] Funding Source: National Science Foundation
Recently, dual-catalytic strategies towards the decarboxylative elimination of carboxylic acids have gained attention. Our lab previously reported a photoredox/cobaloxime dual catalytic method that allows the synthesis of enamides and enecarbamates directly fromN-acyl amino acids and avoids the use of any stoichiometric reagents. Further development, detailed herein, has improved upon this transformation's utility and further experimentation has provided new insights into the reaction mechanism. These new developments and insights are anticipated to aid in the expansion of photoredox/cobalt dual-catalytic systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据