期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 37, 页码 8205-8209出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000844
关键词
conformation; IR spectroscopy; kinetic isotope effects; phosphorus acids; quantum mechanical tunneling
资金
- National Natural Science Foundation of China [21673147]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Metaphosphorous acid (HOPO), a heavy analogue of nitrous acid (HONO), has been generated insyn-andanti-conformations in the gas phase. Surprisingly,anti-HOPO is highly unstable and it undergoes rapid rotamerization tosyn-HOPO via hydrogen-atom tunneling (HAT) with a lifetime of 10 min in N-2-matrix at 2.8 K. More information can be found in the Communication by X. Zeng et al. (DOI:10.1002/chem.202000844).
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