期刊
CHEMISTRY OF MATERIALS
卷 32, 期 8, 页码 3325-3334出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.0c00648
关键词
-
资金
- U.S. Department of Energy, Office of Science, Basic Energy Sciences [DESC0020234]
- Sloan Research Fellowship in Chemistry from the Alfred P. Sloan Foundation
This perspective presents an overview of how confinement can be used to tune electrochemical reactivity and the concept of using molecularly pillared 2D and layered materials to experimentally study this phenomenon. Many theoretical and computational studies have shown that the confinement of liquid-phase reactants to nano- or subnanometer spaces influences their electrochemical reactivity. While confinement is ubiquitous in various high surface area materials used as electrodes, experimental studies of this effect are scarce due to the challenge of deconvoluting the many competing influences on the measured electrochemical signal. This creates an exciting opportunity for the synthesis of well-defined materials platforms capable of confining liquid electrolytes and reactants for understanding electrochemical reactivity under confinement. In particular, a precise confinement geometry can be achieved with the use of 2D and layered materials whose interlayers have been tuned with the use of molecular pillars.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据