期刊
CHEMISTRY LETTERS
卷 49, 期 8, 页码 944-946出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200208
关键词
Lead-free; Perovskite solar cells; Sb(V) based-complexes
资金
- Takahashi Industrial and Economic Research Foundation [06-003-154]
- [15K05597]
Lead halide perovskite has emerged as a promising photovoltaic material due to its excellent power conversion efficiency (PCE). However, the toxicity problem of lead-based perovskite hampers the commercialization of perovskite solar cells. Here, we develop several Sb(V) complexes with pyridyl cations and serve as absorber layer for lead-free perovskite solar cells. The designed complexes were based on 4-tert-butylpyridine (tBP) and N-ethylpyridinium (N-EtPy) cations with bandgaps of 2.01 eV and 1.95 eV, which showed their potential for solar cells and optoelectronic applications. We also found a chemical rule for stable Sb complexes in terms of the bond connectivity of pnictogen-antimony. Initial studies produce a solar cell with a PCE of 0.9% and offer inspiration for further exploration of environment-friendly perovskite families.
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