期刊
CHEMISTRY LETTERS
卷 49, 期 7, 页码 867-869出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200297
关键词
Organocatalyst; Michael reaction; Domino reaction
资金
- JSPS KAKENHI [JP20H04801, JP19H05630]
Substituted chiral hydrindanes were synthesized as single isomers in almost enantiopure forms through a one-pot process that proceeds via the diphenylprolinol silyl ether mediated-domino Michael/Michael reaction of alpha,beta-unsaturated aldehydes and 3-hexene-2,5-dione, and a subsequent intramolecular aldol condensation of the generated cyclopentanone intermediate.
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