期刊
CHEMICAL ENGINEERING JOURNAL
卷 387, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.124130
关键词
Phthalocyanine; Dopant-free; Hole transport material; Mesoporous; Perovskite solar cell
资金
- National Natural Science Foundation of China [21805114, 21905119]
- Natural Science Foundation of Jiangsu province [BK20180867, BK20180869]
- China Postdoctoral Science Foundation [2019M651741]
- Six talent peaks project in Jiangsu province [XNY066]
- Jiangsu distinguished professor project
- Jiangsu University Foundation [17JDG032, 17JDG031]
- High-tech Research Key laboratory of Zhenjiang [SS2018002]
Many researches manifest that the presences of dopant and additive in hole transport layer (HTL) accelerate the degradation of perovskite solar cell (PSC). Therefore, in terms of enhancing stability, it is promising to develop dopant-free hole transport materials (HTMs). Herein, a methoxy substituted copper(II) phthalocyanine CuPc-(OMe)(8) was synthesized and successfully applied as dopant-free HTM in the PSCs. The optimized PSC devices based on the dopant-free CuPc-(OMe)(8) achieve the highest efficiency of 18.3%, which is competitive with traditional doped Spiro-OMeTAD. More importantly, an impressively superior long-term stability is represented by dopant-free CuPc-(OMe)(8) based device. These results highlight that CuPc-(OMe)(8) is a promising dopant-free HTM for application in PSCs.
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