期刊
CHEMCATCHEM
卷 12, 期 17, 页码 4339-4345出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202000466
关键词
electrocatalytic oxygen evolution; morphology and composition regulation; Prussian blue analogues; transition-metal phosphide
资金
- Anhui province key research and development program project [201904d07020001]
Prussian blue analogues (PBAs) are mostly binary metallic compounds with a cubic structure, which greatly limits the structure and component of derived transition-metal phosphides (TMPs) and affects their catalytic activities. This work focuses on regulating the morphology and composition of the PBA at the front-end to optimize the OER performance of the derived TMP. By temperature control surfactant desorption ability, we obtain a series of ternary FeCoNi (FCN-PBAs). With the increase of temperature, their morphologies change from truncated octahedrons to cubic octahedrons and truncated cubes, in which the Fe content basically remains unchanged and the Co/Ni ratio gradually decreased. Due to the synergistic effect among ternary TMPs, all phosphidation products (FCN-P) exhibit better OER activities than RuO2, among which FCN-40-P shows the best performance. As confirmed by XPS analyses, the appropriate chemical composition enhances the oxidizabilityof TM species, promotes the chemical adsorption of OH-, and accelerates OER kinetics.
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