期刊
CHEMCATCHEM
卷 12, 期 17, 页码 4224-4241出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202000418
关键词
Biomass; Fuels and chemicals; Mesoporous inorganic materials; Phosphorus-modified catalysts; Syngas conversion
资金
- National Research Foundation (NRF) of South Korea [NRF-2018 M3D3 A1 A01018009, NRF-2020R1 A2 C2006052]
Phosphorus-modified mesoporous inorganic materials play crucial roles in the valorization of lignocellulosic biomass materials such as syngas (CO and H-2), carbohydrate sugars and lignin. This review summarizes the recent advances on the Co-impregnated and phosphorus-modified gamma-Al(2)O(3)and SiO(2)catalysts for production of liquid hydrocarbon fuelsviaFischer-Tropsch synthesis (FTS) reaction of syngas as well as metal phosphates or precious (Pt and Ru) metals-supported on the metal phosphates for production of furanic compounds, levulinic acid, aromatics and fuel commodities from carbohydrate sugars and lignin. These phosphorus-modified materials play key roles in the syngas as well as biomass conversion processes due to their tunable surface properties and mesoporous structures. Phosphorus to metal ratios of inorganic materials with their porosity, calcination temperatures of metal phosphates, natures of biomass feedstocks, and reaction variables significantly affect yields of both hydrocarbon fuels and value-added chemicals. This short review mainly focusses on the various applications of those mesoporous catalysts and supports, and strategies for effective catalytic transformations of lignocellulosic biomass-derived feedstocks.
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