期刊
CATALYSIS COMMUNICATIONS
卷 137, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.catcom.2020.105927
关键词
Cobalt; Heterogeneous catalysis; Quinoxalines; Imines; Mechanistic investigations
资金
- Science and Engineering Research Board (SERB), India
- Council for Industrial and Scientific Research (CSIR), India
- Indian Institute of Technology Kanpur
- UGC
- Department of Science and Technology (DST)
- IITK
A nitrogen doped carbon supported cobalt catalyzed efficient synthesis of imines and quinoxaline motifs is reported. Co(OAc)(2)-Phen/Carbon-800 (Co-phen/C-800) showed the superior reactivity compared to other materials prepared at different temperature, in the synthesis of quinoxalines by the coupling between diamines and diols. Moreover, applying the transfer hydrogenation and acceptorless dehydrogenative coupling strategy, imines and quinoxaline derivatives were synthesized from the nitro compounds. The practical applicability of this protocol was demonstrated by the gram-scale synthesis and the reusability of the catalyst upto 8th cycle. Furthermore, several kinetic experiments were carried out to realize the probable mechanism.
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