期刊
CARBON
卷 159, 期 -, 页码 83-93出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.12.021
关键词
Zeolite imidazolate framework (ZIF); Carbon materials; Metal particles; Heterogeneous interfaces; Microwave absorption performance
资金
- National Natural Science Foundation of China [51602259]
- Natural Science Basic Research Plan in Shaanxi Province of China [2019JQ-222]
- Fundamental Research Funds for the Central Universities [310201911cx037]
Rational manipulation of zeolite imidazolate framework derived carbon microwave absorbers is highly significant, but still remains a challenge. Herein, three kinds of multi-metallic doped N-implanted carbon polyhedrons (NCP), named Mo-NCP, W-NCP and MoW-NCP, with tailored composition and unique structure derived from the pyrolysis of hybrid zeolite imidazolate framework (HZIF) precursors have been fabricated. The architecture can be tuned from rhombic dodecahedral shape for W-NCP and MoW-NCP to chamfered cube shape for Mo-NCP, thereby adjusting their impedance matching and microwave attenuation. With a filler loading of 30 wt%, the obtained absorbers possess not only strong absorption capability, but also wide absorption bandwidth compared with NCP. As the best, the minimum R-L of MoW-NCP is up to -55.6 dB at 11.3 GHz and the absorption bandwidth exceeding -10 dB remarkably reaches as wide as 8.8 GHz with a thickness of 2.8 mm. The excellent performance may be ascribed to the multi-heterogeneous interfaces and smaller metal nanoparticles, resulting in strong dipolar/interfacial polarizations, multiple scatterings, enhanced conduction loss and promoted impedance matching. This study not only broadens the limitation of traditional bimetallic ZIFs, but also pave a novel avenue for the design of novel N-implanted carbon microwave absorbers with tunable chemical composition and multi-heterogeneous interfaces. (C) 2019 Elsevier Ltd. All rights reserved.
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