期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 93, 期 9, 页码 1065-1069出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20200122
关键词
Base catalyst; Organoboron; 1,2-Addition
资金
- JSPS KAKENHI [JP17H06449, JP18H01971]
- Kanazawa University SAKIGAKE project 2018
The KHMDS-catalyzed tertiary alkylation of aldehydes, ketones or imines using tertiary benzylic organoboronates is reported. This protocol permitted the use of tertiary benzylic alkylboronates as the tertiary alkyl anion for construction of highly congested contiguous sp(3) carbon centers. The mild and transition-metal-free reaction conditions are attractive features of the protocol.
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