期刊
CATALYSIS TODAY
卷 266, 期 -, 页码 168-174出版社
ELSEVIER
DOI: 10.1016/j.cattod.2015.08.013
关键词
MCPA; 2,4-D; 4-Chlorophenol; Herbicides; Hydrodechlorination; Photocatalysis
The degradation of chlorinated herbicides (MCPA and 2,4-D) and 4-chlorophenol (4-CP) by photocatalytic oxidation (PCO) and the combination of catalytic hydrodechlorination (HDC) and photocatalysis, at ambient conditions, has been studied. Commercial TiO2 (P25) and Pd/Al2O3 catalysts were used for PCO and HDC, respectively. MCPA and 2,4-D were transformed upon photo-oxidation to intermediate products and almost total mineralization was achieved. However, in the case of 4-CP, a conversion of only 82% of chloride formation and 87% TOC were obtained. In spite of the fact that the HDC reaction resulted in a total dechlorination of organochlorinated pollutants combined with an important decrease of the effluent ecotoxicity, the percentage of mineralization obtained in the combined process (HDC-PCO) was slightly lower than in the PCO treatment. Thus, the HDC-PCO process is not justified versus a single PCO treatment. (C) 2015 Elsevier B.V. All rights reserved.
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