期刊
CATALYSIS TODAY
卷 263, 期 -, 页码 46-51出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2015.09.044
关键词
Coke oven gas; Water-gas shift reaction; Hydrogen production; Thermodynamic calculation; Cu/ZnO/Al2O3
资金
- National Natural Science Foundation of China [21201122]
- National High Technology Research and Development Program of China [2006AA11A189]
A study of H-2-rich syngas derived from coke oven gas for hydrogen production on Cu/ZnO/Al2O3 catalyst has been performed by water-gas shift reaction (WGSR). The theoretical thermodynamic equilibrium on the reaction temperature, steam/carbon (S/C) ratio and the high amount of H-2 and CH4 in the syngas have been considered in this work. From theoretical calculations and experiment results, it can be seen that the catalyst Cu/ZnO/Al2O3 can effectively and selectively transform H2O and CO to H-2 and CO2 under an atmosphere of 2.5 vol.% CH4 and 75.0 vol.% H-2. The high catalytic activity is closely correlated with the strong structural interaction of aurichalcite and hydrotalcite phases. Moreover, the thermal stability of the Cu/ZnO/Al2O3 catalyst was also studied by calcining at different temperatures. No obvious decrease in CO conversion was detected, suggesting that the catalyst had high heat-resisting ability due to the enhancement of the synergistic interaction in structural precursors. (C) 2015 Elsevier B.V. All rights reserved.
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