4.7 Article

Construction of 2D/2D/2D rGO/p-C3N4/Cu3Mo2O9 heterostructure as an efficient catalytic platform for cascade photo-degradation and photoelectrochemical activity

期刊

APPLIED SURFACE SCIENCE
卷 511, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2020.145469

关键词

Ternary composite; Photocatalysis; Antibiotic; Langmuir-Hinshelwood; Mineralization

资金

  1. National Research Foundation of Korea (NRF) - Korean government (MSIT) [2018R1A2B2006094]
  2. Dongguk University [S-2019-G0001-00050]
  3. National Research Foundation of Korea [2018R1A2B2006094] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

向作者/读者索取更多资源

Well-designed heterostructure photocatalysts with effective interfacial contacts have attracted significant attention, owing to their enhanced visible-light absorption and optimal charge separation efficiency. Herein, novel visible-light-responsive heterostructure photocatalysts composed of reduced graphene oxide (rGO)/protonated g-C3N4 (p-CN)/Cu3Mo2O9 (CMO) were constructed through a facile hydrothermal method. In particular, the ternary composite with 20 wt% of CMO content (rGO/p-CN/CMO-20) was optimized as an efficient catalyst for tetracycline (TC) degradation. The TC degradation rate of the rGO/p-CN/CMO-20 catalyst was found to be similar to 41, 15, 22, 7, and 14 times higher than those of rGO, p-CN, CMO, p-CN/CMO-20, and rGO/CMO-20, respectively. The outstanding photocatalytic activity could be attributed to the enhanced visible-light absorption, synergistic effect among the components, high specific surface area, good interfacial contact, efficient separation and transfer of photo-generated charge-carriers as well as good photostability. In addition, reactive radical scavenging and band edge position analyses provided evidence for a possible mechanism of the enhanced photocatalytic activity exhibited by rGO/p-CN/CMO-20. Mineralization with 60% total organic carbon reduction was achieved during the 60 min treatment of the optimized sample. The kinetic analysis revealed that the photocatalytic degradation obeyed the Langmuir-Hinshelwood kinetic model. The primary intermediates were identified through liquid chromatography-mass spectrometry, and a photo-degradation pathway was tentatively proposed. This work will provide new routes for the design and construction of efficient two-dimensional rGO/p-CN-decorated heterostructures and their use in environmental decontamination.

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