期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 277, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119170
关键词
PbBiO2Br atomic layers; oxygen vacancies; photocatalysts; CO2 reduction
资金
- National Natural Science Foundation of China [21476098, 21471069, 21576123]
- U.S. DOE Office of Science Facility, at Brookhaven National Laboratory [DE-SC0012704]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX17_1792]
- Virginia Tech
The effect of surface defects on photogenerated carriers separation and CO2 activation is not always clear. Herein, the well-defined bimetallic oxyhalide PbBiO2Br atomic layers with tunable oxygen vacancies (OVs) concentrations have been synthesized and investigated to reveal the role of OVs for photocatalytic CO2 conversion. Ultrafast transient absorption spectroscopy and theoretical calculations revealed that the rich oxygen vacancies (ROV) in PbBiO2Br atomic layers facilitated the transfer of photogenerated electrons from the internal structure to surface and prolonged their lifetime on the surface OVs. PbBiO2Br atomic layers with ROV demonstrated superior CO2 reduction performance with enhanced CO evolution rate of 4.58 mu mol g h(-1) in water under visible light irradiation, which was 2.05 and 10.90 times higher than that of deficient oxygen vacancies (DOV) PbBiO2Br atomic layers and bulk PbBiO2Br, respectively. Intermediate products of CO2 conversion were investigated by in-situ Fourier-transform infrared spectroscopy and the corresponding reaction mechanism was proposed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据