4.8 Article

Fabrication of BiVO4 photoanode cocatalyzed with NiCo-layered double hydroxide for enhanced photoactivity of water oxidation

期刊

APPLIED CATALYSIS B-ENVIRONMENTAL
卷 263, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.apcatb.2019.118280

关键词

BiVO4; NiCo-LDH; Photoelectrochemical water splitting; Electric deposition

资金

  1. National Natural Science Foundation of China [21663027, 21808189, 21962018]
  2. Science and Technology Support Project of Gansu Province [1504GKCA027]
  3. Program for the Young Innovative Talents of Longyuan
  4. Program for Innovative Research Team [NWNULKQN-15-2]
  5. Fundamental Research Funds for the Central Universities of Chang'an University [300102299304]

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Modifying a semiconductor photoanode with an oxygen evolution cocatalyst is an effective method for improving the photoelectrochemical (PEC) water decomposition efficiency. Here, PEC efficiency of BiVO4 electrode is enhanced by constructing a NiCo-LDH/BiVO4 heterojunction. Under the synergistic effect of NiCo-LDH and BiVO4, the photocurrent, incident photon-to-current conversion efficiency and hydrogen production of NiCo-LDH/BiVO4 electrode have been significantly improved, which are mainly attributed to the enhancement of internal light absorption, photogenerated carriers transfer and separation.

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