期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 35, 页码 14869-14876出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202003663
关键词
dendrite growth; fluorinated aromatic diluent; electrolytes; lithium metal batteries; solid electrolyte interphase
资金
- National Research Foundation of Korea [NRF-2018R1A2A1A19023146, NRF-2018M1A2A2063340]
- Institute of Engineering Research (IER) at Seoul National University
In lithium metal batteries, electrolytes containing a high concentration of salts have demonstrated promising cyclability, but their practicality with respect to the cost of materials is yet to be proved. Here we report a fluorinated aromatic compound, namely 1,2-difluorobenzene, for use as a diluent solvent in the electrolyte to realize the high-concentration effect. The low energy level of the lowest unoccupied molecular orbital (LUMO), weak binding affinity for lithium ions, and high fluorine-donating power of 1,2-difluorobenzene jointly give rise to the high-concentration effect at a bulk salt concentration near 2 m, while modifying the composition of the solid-electrolyte-interphase (SEI) layer to be rich in lithium fluoride (LiF). The employment of triple salts to prevent corrosion of the aluminum current collector further improves cycling performance. This study offers a design principle for achieving a local high-concentration effect with reasonably low bulk concentrations of salts.
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