期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 29, 页码 11754-11757出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202002710
关键词
aminocarbene complexes; enynes; hydroaminative cyclization; rhodium; secondary amines
资金
- Promotion of Science (JSPS) KAKENHI [JP17K19126, JP16H04150, JP15H05839]
- JSPS KAKENHI [JP18H04271]
- Asahi Glass Foundation
- Research Grant of Keio Leading-edge Laboratory of Science Technology
We report a hydroaminative cyclization of enynes using phosphine-quinolinolato rhodium catalysts. The hydroaminative cyclization of 2-vinylphenylacetylene derivatives with secondary amines gives 2-aminoindenes in good yields. The reaction is considered to proceed through carbon-carbon bond formation on a catalytically generated aminocarbene ligand.
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