期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 26, 页码 10610-10618出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202002673
关键词
coercive field; magnetic hysteresis; magnetism; molecular magnetism; single-chain magnets
资金
- National Key R&D Program of China [2018YFA0306002]
- National Natural Science Foundation of China [21971123, 21622105, 21861130354]
- National Natural Science Foundation of Tianjin [18JCJQJC47200]
- Ministry of Education of China [B12015]
- Royal Society through a Newton Advanced Fellowship
- NSF [CHE-1800252]
Lanthanide permanent magnets are widely used in applications ranging from nanotechnology to industrial engineering. However, limited access to the rare earths and rising costs associated with their extraction are spurring interest in the development of lanthanide-free hard magnets. Zero- and one-dimensional magnetic materials are intriguing alternatives due to their low densities, structural and chemical versatility, and the typically mild, bottom-up nature of their synthesis. Here, we present two one-dimensional cobalt(II) systems Co(hfac)(2)(R-NapNIT) (R-NapNIT=2-(2 '-(R-)naphthyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, R=MeO or EtO) supported by air-stable nitronyl nitroxide radicals. These compounds are single-chain magnets and exhibit wide, square magnetic hysteresis below 14 K, with giant coercive fields up to 65 or 102 kOe measured using static or pulsed high magnetic fields, respectively. Magnetic, spectroscopic, and computational studies suggest that the record coercivities derive not from three-dimensional ordering but from the interaction of adjacent chains that compose alternating magnetic sublattices generated by crystallographic symmetry.
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