期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 27, 页码 10797-10801出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201916314
关键词
alkaline fuel cells; electrocatalysts; hydrogen evolution reaction; hydrogen oxidation reaction; strain effect
资金
- EPFL
- Ministry of Science and Technology of Taiwan [MOST 108-2628-M-002-004-RSP]
The hydroxide-exchange membrane fuel cell (HEMFC) is a promising energy conversion device. However, the development of HEMFC is hampered by the lack of platinum-group-metal-free (PGM-free) electrocatalysts for the hydrogen oxidation reaction (HOR). Now, a Ni catalyst is reported that exhibits the highest mass activity in HOR for a PGM-free catalyst as well as excellent activity in the hydrogen evolution reaction (HER). This catalyst, Ni-H-2-2 %, was optimized through pyrolysis of a Ni-containing metal-organic framework precursor under a mixed N-2/H-2 atmosphere, which yielded carbon-supported Ni nanoparticles with different levels of strains. The Ni-H-2-2 % catalyst has an optimal level of strain, which leads to an optimal hydrogen binding energy and a high number of active sites.
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