期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 24, 页码 9534-9541出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202000255
关键词
cation-pi interactions; supramolecular chemistry; supramolecular self-assembly
资金
- National Science Foundation of China [21674086, 21873094]
- Natural Science Basic Research Plan in Shaanxi Province of China [2020JC-20, 2018JZ2003]
- Fundamental Research Funds for the Central Universities [3102019PY003]
- student innovation fund of Northwestern Polytechnical University [201910699029]
- Key Research Program of Frontier Sciences, Chinese Academy of Sciences [ZDBS-LY-SLH033]
The cation-pi interaction is a strong non-covalent interaction that can be used to prepare high-strength, stable supramolecular materials. However, because the molecular plane of a cation-containing group and that of aromatic structure are usually perpendicular when forming a cation-pi complex, it is difficult to exploit the cation-pi interaction to prepare a 2D self-assembly in which the molecular plane of all the building blocks are parallel. Herein, a double cation-pi-driven strategy is proposed to overcome this difficulty and have prepared 2D self-assemblies with long-range ordered molecular hollow hexagons. The double cation-pi interaction makes the 2D self-assemblies stable. The 2D self-assemblies are to be an effective carrier that can eliminate metal-nanoparticle aggregation. Such 2D assembly/palladium nanoparticle hybrids are shown to exhibit recyclability and superior catalytic activity for a model reaction.
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