期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 32, 页码 13192-13202出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202001031
关键词
catalysis; molecular switches; photochromism; self-assembly; stiff-stilbene
资金
- European Research Council [802830]
- Netherlands Organization for Scientific Research [VI.Vidi.192.049]
- European Research Council (ERC) [802830] Funding Source: European Research Council (ERC)
Stiff-stilbene, a sterically restricted fused ring analogue of stilbene, has been regularly used as a model compound in theoretical studies of stilbene photoisomerization. Lately, owing to its excellent photoswitching properties, it is increasingly being applied to reversibly control the properties and function of chemical as well as biological systems. Stiff-stilbene photoswitches possess a number of advantageous properties including a high quantum yield for photoisomerization and a high thermal stability. Furthermore, they undergo a large geometrical change upon isomerization and their synthesis is straightforward. Herein, we provide an overview of the basic properties of stiff-stilbene and of recent applications in supramolecular chemistry, catalysis, and biological systems.
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