期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 24, 页码 9631-9638出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202001191
关键词
conducting redox polymers; electrical energy storage; electrochemistry; organic battery; quinones
资金
- Swedish Energy Agency
- Carl Trygger Foundation
- Olle Engqvist Byggmstare Foundation
- Forsk Foundation
- Research Council Formas
Electrodes based on organic matter operating in aqueous electrolytes enable new approaches and technologies for assembling and utilizing batteries that are difficult to achieve with traditional electrode materials. Here, we report how thiophene-based trimeric structures with naphthoquinone or hydroquinone redox-active pendent groups can be processed in solution, deposited, dried and subsequently polymerized in solid state to form conductive (redox) polymer layers without any additives. Such post-deposition polymerization offers efficient use of material, high mass loading (up to 10 mg cm(-2)) and good flexibility in the choice of substrate and coating method. By employing these materials as anode and cathode in an acidic aqueous electrolyte a rocking-chair proton battery is built. The battery shows good cycling stability (85 % after 500 cycles), withstands rapid charging, with full capacity (60 mAh g(-1)) reached within 100 seconds, allows for direct integration with photovoltaics, and retains its favorable characteristics even at -24 degrees C.
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