期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 13, 页码 2701-2708出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000214
关键词
Phosphinyl Allenes; Oxyalkenylation; Visible Light; Palladium Catalysis; Conjugated Tertiary Allylic Alcohol derivatives
资金
- Foundation Research Project of Jiangsu Province (The Natural Science Foundation) [BK20180513, BK20191305]
- Fundamental Research Funds for the Central Universities (NJAU) [KYDZ201904, KJQN201719]
- Qing-Lan Project of Jiangsu Provincial Department of Education
- 333 High Level Talent Project of Jiangsu Province
A highly regio- and stereoselective oxyalkenylation of phosphinyl allenes is revealed for the first time. This protocol, merging visible light photoredox and palladium catalysis, provides a direct approach to conjugated tertiary allylic alcohol derivatives with broad functional group tolerance in moderate to excellent yields. Mechanistic studies suggest that, although two possible pathways exist in the transformation, radical oxyalkenylation promoted by visible light photoredox takes over the major pathway.
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