期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 14, 页码 2990-2996出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000257
关键词
photocatalysis; iridium; defluoroborylation; N-heterocyclic carbene boranes; trifluoromethyl alkenes
资金
- National Natural Science Foundation of China [21562052, 21462055]
- National First-Rate Construction Discipline of Guizhou Province (Pharmacy) [YLXKJS-YX-04]
A photoredox-catalyzed defluoroborylation of trifluoromethyl alkenes with N-heterocyclic carbene boranes is described for the synthesis of gem-difluoroallylboranes. This protocol exhibits a broad substrate scope and good functional group compatibility, which enables the late-stage functionalization of structurally complex compounds. Further transformations of the defluoroborylation products to valuable CF2-containing molecules are also demonstrated.
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